3-Butyn-2-one, 98%, Each
$ 238.80
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Details
3-Butyn-2-one was used in the synthesis of clerodane diterpenoid (±)-sacacarin. It was used as substrate in stereoselective, conjugate arylation mediated by gallium(III) chloride leading to (E)-α,β-unsaturated ketones. 3-Butyn-2-one undergoes asymmetric double-Michael reaction with ortho-tosylamidophenyl malonate catalyzed by chiral aminophosphines to yield indolines2. It undergoes double Michael reaction with nitrogen-containing tethered diacid to give pipecolic acid derivatives. 3-Butyn-2-one, is used as a reactant with Dimethyl acetone-1,3-dicarboxylate, under mild conditions to give a benzenoid product via a Michael addition - aldol cyclization process.
Additional Information
SKU | 10097245 |
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UOM | 5g |
UNSPSC | 12352100 |
Manufacturer Part Number | L0552706 |
CAS Number | 1423-60-5 |
Is Hazardous | Yes |
HS Code | 2914190000 |
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UN Number | UN 1992 |
Proper Shipping Name | 3-Butyn-2-one |
Packaging Group | PG II |
Hazardous Class | 3 |
Label | |
Molecular Formula | C4H4O |
EC Number | 215-834-2 |
HIN | 336 |
Hazard Statement | H225-H300-H315-H319-H335 |
Precautionary Statements | P210-P261-P264-P301+P310-P305+P351+P338-P233-P240-P241+P242+P243-P260-P262-P270-P271-P280-P284-P301+P310+P330-P302+P352+P310+P361+P364-P304+P340+P310-P305+P351+P338+P337+P313-P370+P378-P403+P233-P405-P501-P301+P310a-P303+P361+P353-P501a |
Risk Statements | 28-36/37/38-11-15-10 |
GHS | GHS02,GHS06 |
GHS (Pictogram) | |
Safety Statements | 45-36/37/39-28A-26-16-43-7/8-7/9-24/25 |
Hazard Code | F,T+,T,Xi,E,X |
Signal Word | Danger |